The Application of Facilitated Ion Transfer Across Membrane Stabilized Interface Between tow Immiscible Electrolyte Solutions in Clinical Analysis

dc.contributor.advisorHundhammer, B.(PhD)
dc.contributor.authorBerhanu, Tarekegn
dc.date.accessioned2018-06-25T09:48:42Z
dc.date.accessioned2023-11-09T16:17:56Z
dc.date.available2018-06-25T09:48:42Z
dc.date.available2023-11-09T16:17:56Z
dc.date.issued1994-06
dc.description.abstractAC and DC voltammetry and flow injection amperometry methods were employed in this work. The influence of ionophores on the facilitated transfer of K+ and Na+ ions across membrane stabilized water/nitrobenzene interface was investigated. According to this investigation benzo 15 crown 5 (B15C5) was found best for K+ ion and dibenzo 24 crown 8 (DB24C8) for Na+. B15C5 was an appropriate ionophore in simultaneous determination of K+ and Na+ ions. DB24C8 was found to be poor in this regard. Stability constants of metal-ionophore complex were estimated. The values forK+ -ionophore (K-DB24C8, KDB18C6) were in good agreement with literature values, while those of Na+-ionophores (Na-DB24C8, Na-DB18C6) are higher than the literature values. Concentrations of Na+ and K+ in blood serum were determined simultaneously using flow injection amperometry and flame photometry. The results obtained from voltammetric and flow injection amperometric investigations indicate that the membrane stabilized interface is a promising as a voltammetric sensor in clinical analysis of blood electrolytesen_US
dc.identifier.urihttp://etd.aau.edu.et/handle/12345678/3141
dc.language.isoenen_US
dc.publisherAddis Ababa Universtyen_US
dc.subjectAC and DC Voltammetryen_US
dc.titleThe Application of Facilitated Ion Transfer Across Membrane Stabilized Interface Between tow Immiscible Electrolyte Solutions in Clinical Analysisen_US
dc.typeThesisen_US

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