The Application of Facilitated Ion Transfer Across Membrane Stabilized Interface Between tow Immiscible Electrolyte Solutions in Clinical Analysis
dc.contributor.advisor | Hundhammer, B.(PhD) | |
dc.contributor.author | Berhanu, Tarekegn | |
dc.date.accessioned | 2018-06-25T09:48:42Z | |
dc.date.accessioned | 2023-11-09T16:17:56Z | |
dc.date.available | 2018-06-25T09:48:42Z | |
dc.date.available | 2023-11-09T16:17:56Z | |
dc.date.issued | 1994-06 | |
dc.description.abstract | AC and DC voltammetry and flow injection amperometry methods were employed in this work. The influence of ionophores on the facilitated transfer of K+ and Na+ ions across membrane stabilized water/nitrobenzene interface was investigated. According to this investigation benzo 15 crown 5 (B15C5) was found best for K+ ion and dibenzo 24 crown 8 (DB24C8) for Na+. B15C5 was an appropriate ionophore in simultaneous determination of K+ and Na+ ions. DB24C8 was found to be poor in this regard. Stability constants of metal-ionophore complex were estimated. The values forK+ -ionophore (K-DB24C8, KDB18C6) were in good agreement with literature values, while those of Na+-ionophores (Na-DB24C8, Na-DB18C6) are higher than the literature values. Concentrations of Na+ and K+ in blood serum were determined simultaneously using flow injection amperometry and flame photometry. The results obtained from voltammetric and flow injection amperometric investigations indicate that the membrane stabilized interface is a promising as a voltammetric sensor in clinical analysis of blood electrolytes | en_US |
dc.identifier.uri | http://etd.aau.edu.et/handle/12345678/3141 | |
dc.language.iso | en | en_US |
dc.publisher | Addis Ababa Universty | en_US |
dc.subject | AC and DC Voltammetry | en_US |
dc.title | The Application of Facilitated Ion Transfer Across Membrane Stabilized Interface Between tow Immiscible Electrolyte Solutions in Clinical Analysis | en_US |
dc.type | Thesis | en_US |