Attempts on synthesis and characterization of Cu (II) complex with a 2, 2’-dipyridylamine derivative Graduate Project (Chem.774) Submitted to School of Graduate Studies Addis Ababa
| dc.contributor.advisor | Raju V.J.T. (Professor) | |
| dc.contributor.author | Haile Tesfaye | |
| dc.date.accessioned | 2018-06-26T06:24:55Z | |
| dc.date.accessioned | 2023-11-09T16:17:59Z | |
| dc.date.available | 2018-06-26T06:24:55Z | |
| dc.date.available | 2023-11-09T16:17:59Z | |
| dc.date.issued | 2010-07 | |
| dc.description.abstract | The ligand dpamc (2,2’-dipyridylammoniumchloride) has been synthesized from dpa (2,2’-dipyridylamine) and acyl chloride via acylation reaction and characterized on the basis of NMR , UV/Vis and elemental analysis. The Cu (II) complex of this ligand was also synthesized and characterized on the basis of spectral data (UV/Vis, AAS), molar conductance, magnetic susceptibility, and elemental analysis. The complex formed is proposed to have a square planar geometry. The ratio of the ligand to Cu (II) in the complex is 2:1 in which each dpa unit acts as a bidentate ligand, coordinating through both pyridyl nitrogens to form a six-membered chelate ring. The Cu (II) complex is a 1:2 electrolyte implying that there are two chloride ions with a complex. The chloride content in the outer sphere of the complex was determined by treatment with silver nitrate solution and gave a positive result. Key words: 2, 2’-dipyridylamine, 2, 2’-dipyridylammoniumchloride, 2, 2’- dipyridylacetamide, Acyl chloride, Cu(II) complex | en_US |
| dc.identifier.uri | http://etd.aau.edu.et/handle/12345678/3427 | |
| dc.language.iso | en | en_US |
| dc.publisher | Addis Ababa Universty | en_US |
| dc.subject | 2, 2’-Dipyridylamine | en_US |
| dc.subject | 2, 2’-Dipyridylammoniumchloride | en_US |
| dc.subject | 2, 2’- Dipyridylacetamide | en_US |
| dc.subject | Acyl chloride | en_US |
| dc.subject | Cu(II) complex | en_US |
| dc.title | Attempts on synthesis and characterization of Cu (II) complex with a 2, 2’-dipyridylamine derivative Graduate Project (Chem.774) Submitted to School of Graduate Studies Addis Ababa | en_US |
| dc.type | Thesis | en_US |