Molecular Design, Synthesis and Characterization of Conjugated Polymers for Application In Organic Optoelectronic
No Thumbnail Available
Date
2017-06-03
Authors
Journal Title
Journal ISSN
Volume Title
Publisher
Addis Ababa University
Abstract
Solar cells are considered as one of the most promising renewable energy technologies as they
harvest the energy of the sun to generate electricity. Organic photovoltaics based on conjugated
polymers are envisioned to generate electricity at very low cost compared with the classical
silicon-based photovoltaics. Up till now, several donor-acceptor alternating polymers were
designed, synthesized and utilized for polymer solar cells (PSCs). Power conversion efficiencies
exceeding 10% have been registered from such devices. However, further optimization of the
conjugated polymer structure is required to attain efficiencies high enough to make this
technology economically attractive and thus, the main focus of this work was to design and
synthesize new conjugated polymers and to characterize their photovoltaic performances in solar
cell devices.
In order to achieve high performance with organic bulk heterojunction (BHJ) cells, it is very
crucial to develop donor photoactive materials which have suitable molecular energy levels.
Donor conjugated polymers with low-lying highest occupied molecular orbital (HOMO) levels
provide high open circuit voltage (Voc) and thus high efficiencies. In this regard, we designed and
synthesized the high bandgap (> 1.9 eV) conjugated polymer PBDTTS-FTAZ with deep
HOMO energy level from fluorinated benzotriazole acceptor unit and a benzodithiophene-based
donor unit incorporating octylthiol side chains. We observed from the electrochemical studies
that PBDTTS-FTAZ had a deeper HOMO energy level compared to the polymer with octyl side
chain (PBDTT-FTAZ). PBDTTS-FTAZ and PBDTT-FTAZ were used in the fabrication of
BHJ polymer solar cells. The device based on PBDTTS-FTAZ:PC71BM showed an enhanced
Voc of 0.83 V, Jsc of 14.0 mA cm−2, and FF of 0.71, resulting in a much improved PCE of 8.3%,which is among the highest efficiencies recorded for conventional BHJ solar cells based on high
bandgap polymers and the highest efficiency reported to date for benzotriazole-based polymers.
All-polymer solar cells (all-PSC) with conventional and inverted device architectures were also
fabricated using PBDTTS-FTAZ and PBDTT-FTAZ as donors and low bandgap naphthalene
diimide (NDI)-based polymers as acceptors. The two donor polymers presented complementary
absorption spectra to the acceptors PNDI-T10 and N2200, which led to better coverage of the
solar irradiation. The acceptors exhibited high LUMO levels as compared to PCBM. Hence, the
lower-lying HOMO of PBDTTS-FTAZ and the higher-lying LUMO levels of the acceptor
polymers would enable higher Voc in the resulting all-PSCs. The inverted all-PSCs using a
PBDTTS-FTAZ:PNDI-T10 blend active layer attained a high PCE of 6.9% with a Voc of 0.89
V, a Jsc of 12.3 mA cm−2 and FF of 0.63. This PCE was stable without obvious efficiency decay
over 60 days. However, inverted all-PSCs based on PBDTT-FTAZ:PNDI-T10 showed a
moderate PCE of 5.0%.
All-PSCs were also fabricated form PBDTTS-FTAZ and a new acceptor polymer PIID-PyDPP
synthesized from pyridine-flanked diketopyrrolopyrrole (PyDPP) and isoindigo (IID) units. The
PBDTTS-FTAZ:PIID-PyDPP all-PSC exhibited a more complementary absorption spectrum
resulting in an encouraging PCE of 4.2% with a very high Voc of 1.07 V due to its low energy
loss of 0.62 eV. A stability study of this all-PSC revealed that there was no obvious reduction in
PCE and more than 90% of the initial PCE was retained after two weeks.
Inspired by the results of fluorinated benzotriazole-containing high bandgap polymers, laddertype
high bandgap polymers (PIDTT-FTAZ-p, PIDTT-FTAZ-m and PIDT-FTAZ-m) were
synthesized using indacenodithieno[3,2-b]thiophene (IDTT) and indacenodithiophene (IDT) as
donors and fluorinated benzotriazole as acceptor and used as electron-donating materials in BHJ
PSCs. A high Voc of 0.95 V was obtained from the meta-substituted IDT polymer PIDT-FTAZm-
based PSC. The best PCE recorded was 6.4% for the device made from para-substituted
IDTT-based polymer PIDTT-FTAZ-p and PC71BM.Ladder-type high bandgap polymers based on bithiazole and IDTT with (P29) and without (P28)
thiophene π-spacer were also developed for PSCs. Both polymers showed a similar bandgap (2.0
eV), but the polymer with thiophene π-spacer (P29) exhibited a higher molecular weight.
Although P28-based PSC devices showed higher Vocs due to the deeper HOMO energy level of
the polymer, P29 showed a higher PCE of 4.5% with enhanced Jsc of 10.4 mA cm−2 and FF of
0.52.
BHJ solar cells based on photoactive materials need to have broad absorption to harvest more
photon flux and thus maximize the photocurrent and PCE. Random terpolymer and ternary blend
systems have been used to extend the light absorption of the active layer. In this regard, we
synthesized random terpolymers from the electron-rich unit thiophene and electron-deficient
moieties quinoxaline and isoindigo. PSCs fabricated from these terpolymers were compared with
those fabricated from the ternary blends of two alternating polymers to explore the best strategy
for extending the light absorption range. The two approaches showed similar Vocs but different
Jscs. The terpolymer strategy broadened the light absorption range and provided a high PCE of
5.8%. This is due to a high Jsc and high hole mobility. The device fabricated from the ternary
blend exhibited a lower PCE (3.5%) compared to those fabricated from the terpolymers and
alternating polymer blends due to the morphological incompatibility of the donor polymers.
A series of new D-A1-D-A2 random terpolymers were prepared for application in PSCs, in which
fluorinated benzotriazole and thienothiophene-capped diketopyrrolopyrrole (TTDPP) were used
as electron-accepting moieties and thienyl-substituted benzodithiophene as the electron-donating
moiety. The study revealed that varying the ratio of FTAZ/TTDPP significantly affects
absorption and energy levels of the copolymer. The terpolymer with high content of the strong
electron withdrawing units showed strong and broad absorptions between 300–900 nm. The best
PCE of 5.7% with Jsc of 15.70 mA cm−2 was recorded from the device fabricated from the
terpolymer with the highest content of strong acceptor unit (TTDPP) and PC71BM.
In order to study the effect of donor units on the optoelectronic properties of polymers, D-A type
polymers based on triazolopyridine acceptor and BDT and IDT donors were designed and
synthesized. The optical and electrochemical properties of the polymers were tuned by varying
the donor units. Regioregular and regiorandom polymers based on triazolopyridine were also
prepared. In contrast to the regiorandom polymer, the regioregular polymer exhibited relatively
broader absorption and deeper HOMO energy level.
Two D-A alternating polymers (PIDT-TPD, PIDT-2TPD) based on bithienopyrrolodione
(2TPD) and thieno[3,4-c]pyrrole-4,6-dione (TPD) as acceptor units and IDT as donor unit were
designed and prepared for use in optoelectronic devices. In contrast to PIDT-TPD, PIDT-2TPD
showed red-shifted absorption spectra and deeper HOMO and LUMO energy levels. High Vocs
around 1 V were recorded for PSCs fabricated from these polymers.
PIDT-2TPD and PIDT-TPD were used as host polymers to fabricate polymer light-emitting
diodes (PLEDs). PLEDs based on PIDT-2TPD and donor-acceptor donor type NIR-emitting
units showed the best performance in the NIR with external quantum efficiency up to 1.16% with
turn-on voltage of 1.7 V.
PIDT-2TPD was also used as non-fullerene acceptor to fabricate all-polymer photodetectors
with the donor P3HT. The P3HT:PIDT-2TPD blend exhibited spectral response from 300 nm
up to the NIR. External quantum efficiency of 34% and high detectivity of 1.3×1012 Jones was
recorded from P3HT:PIDT-2TPD blend BHJ all-polymer photodetectors.
D–A low bandgap polymers based on unsubstituted benzodithiophene and isoindigo units were
also designed and synthesized. The polymer P39 with more branched side chains, both on the
thiophene and isoindigo units, showed high molecular weight and deep HOMO energy level. The
PSC based on P39:PC71BM showed a high Voc of 0.91 V.
Description
Keywords
Molecular Design, Synthesis, Characterization of Conjugated Polymers, Application In Organic Optoelectronic