Synthesis and Characterization of Nickel(II), Copper(Ii) and Zinc(II) Complexes with 1,10-Phenanthroline-5,6-Dioxime
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Date
2010-06
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Addis Ababa Universty
Abstract
Mononuclear complexes of Zn(II) N,N’ coordinated with phendione and phendioxime and
polynuclear of Ni(II), Cu(II) and Zn(II) complexes of the phendioxime were synthesized and
characterized by direct method. The Ni(II), Cu(II) and Zn(II) species coordinated by N,N’ of the
oximate and phen groups. The Ni(II) complex of the oximate has square-planar geometry and
the phen has octahedral goemetry. And the Cu(II) and Zn(II) complexes of the oximate and the
phen have octahedral geometry. Mononuclear complex of Zn(II) with phendione N,N’
coordinated was the precursor for mononuclear complex of Zn(II) with phedioxime N,N’
octahedral coordinated by the phen group and the hetronuclear complex of Ni(II) with the
mononuclear Zn-phendioxime complex was synthesized and characterized by template method.
The Zn(II) and Ni(II) species coordinated by N,N’ of the phen and oximate groups, respectively.
The Zn(II) moiety coordinated through N,N’ of the phen has octahedral geometry and the Ni(II)
moiety coordinated through N,N’ of the oximate has tetrahedral geometry. Structures of the
ligand and its complex is proposed and formulated according to the elemental analysis, 1H, 13C
NMR, UV-Vis and AAS, molar conductivity and magnetic susceptibility..
Key words: phendione, phendioxime, phen and oximate.
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Keywords
phendione; phendioxime; phen and oximate