Temachwroferrate(III) - Selective Liquid Membhane Electrode Based on Crystal Violet - Studies and Applications.
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Date
1989-06
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Abstract
A 7xW-4 M Crystal Violet tetrachloroferrate(III) extract in
nitrobenzene has been used to construct tetrachlol~}ferrate(III)-selective
liquid IllEITbrane electrode with a PVC support. The electrode body was
made fran too concentric Pyrex glass tubes (lengths 120 mn and internal
diameters 6 & 12mn) with a 11/23 {ITound glass joint at a canron end and
narrower tips at other ends. The experimental conditions have been
established to determine 2.5xlU.- 5 -5x10- 2 M iron(I1I), as tetrachloroferrate(
III) and were found to be 4.0-5.5 M in total chloride and
0.75-1.5 M in HCI with slope of 56.0 mV decade-1 and a detection limit of
7.9x1l'-6 M iron(III). Selectivity studies with 30 anions and cations
have been made to screen the species which may interfere with iron
determination. The electro:\e has been used reliably to measure iron in
mineralized and vitaminized syrup, haematite, htUnan blood, and standard
Sarr[)les with direct standard addition, samDle addition and standard
subtraction notentiOOl0tric techniques. EDTA titrations have also shown
the feasibility of titration with the proposed electrode do\yn to
1x10-4 M iron( III).
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Keywords
Tetrachloroferrate(III)