Determination of some Major and Trace Metals Levels in Korarima (Aframomum Corrorima) Cultivated in the Southern and Southwestern Ethiopia
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Date
2010-07
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Addis Ababa Universty
Abstract
In this study, the concentration levels of major (Ca and Mg), trace (Fe, Zn, Cu,
Co, Cr, Mn, and Ni), and toxic (Cd and Pb) metals were determined in korarima
(Aframomum corrorima) samples collected from southern and southwestern
Ethiopia. The results were compared with the metal levels in the soil collected
from the same area as korarima sample. A wet digestion procedure involving the
use of 3 mL of HNO3 (69-72%) and 1 mL of HClO4 (70%) and modified aqua regia
(HCl:HNO3, 3:1) with hydrogen peroxide (6 mL of aqua regia and 1.5 mL of
H2O2) were used to solubilize metals from the korarima and soil samples,
respectively. Flame atomic absorption spectrometry was used to quantify the
metals levels. The validity of the procedure was checked by spiking experiments
and the recovery value ranges from 88 to 109% for korarima and from 89 to 104%
for soil samples. Calcium and iron were found to be the highest metals
determined in korarima and soil samples, respectively. Manganese is the most
accumulated trace metal in korarima seed samples analyzed and the second
most accumulated trace metal in the soil next to iron. The concentration of
cadmium was within the range 0.9-1 μg/g dry wt in korarima samples. The level
of lead in the korarima samples was below the method detection limit.
Key words: Korarima (Aframomum corrorima), Soil, Wet digestion, FAAS,
Ethiopia.
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Keywords
Korarima (Aframomum corrorima); Soil; Wet digestion; FAAS; Ethiopia.