Solomon, Theodros (Professor)Negash, Asfaw2018-06-132023-11-092018-06-132023-11-092010-06http://etd.aau.edu.et/handle/12345678/759Electrochemical oxidation of catechol has been studied in the presence of imidazole as nucleophile in aqueous solution, using cyclic voltammetry. The results indicate the participation of catechol in 1, 4- Michael reaction with imidazole to form the corresponding catechol thioethers. Based on the observed EC mechanism, the homogeneous rate constants (kfcal) of the reaction of o-benzoquinone with imidazole were estimated by fitting the theoretical working curve with the experimental working curve. Key words: EC mechanism, cyclic voltammetry, catechol and imidazole.enEC mechanism; cyclic voltammetry; catechol and imidazoleStudy of EC mechanism by cyclic voltammetry: Electrochemical oxidation of catechol in the presence of imidazoleThesis